HKEY_CURRENT_USER\Software\Policies\Microsoft\Office\14.0\Outlook\AutoDiscover
Value name: ZeroConfigExchange
Value type: REG_DWORD
Value data: 1
- OR -
If you want to do this using a GPO group policy object, enable this Outlook 2010 Policy on your domain:
User configuration / Policies / Administrative templates / Microsoft Outlook 2010 / Account Settings / Exchange
“Automatically configure profile based on Active Directory Primary SMTP address”
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